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http://dspace.mediu.edu.my:8181/xmlui/handle/123456789/4200| Title: | Electrocatalytic oxidation of b-dicarbonyl compounds using ceric methanesulphonate as mediator |
| Keywords: | electrocatalysis electrooxidation ceric methanesulphonate |
| Issue Date: | 30-May-2013 |
| Publisher: | Sociedade Brasileira de Química |
| Description: | beta-dicarbonyl compounds were oxidized electrocatalytically, with fragmentation and loss of "ch2", using ceric methanesulphonate as a mediator. 2,4-pentanedione yields acetic acid (90%), methyl acetoacetate yields acetic acid (84%) plus methanol and dimethyl malonate yields methanol (64%). For 1,3-diphenyl-1,3-propanedione and 1,3-cyclohexanedione, benzoic acid (61% yield) and glutaric acid (75% yield) were obtained, respectively. Methyl cyanoacetate and malononitrile were inert. |
| URI: | http://koha.mediu.edu.my:8181/jspui/handle/123456789/4200 |
| Other Identifiers: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421998000200007 http://www.doaj.org/doaj?func=openurl&genre=article&issn=01004042&date=1998&volume=21&issue=2&spage=144 |
| Appears in Collections: | Chemistry |
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