Electrocatalytic oxidation of b-dicarbonyl compounds using ceric methanesulphonate as mediator

Please use this identifier to cite or link to this item: http://dspace.mediu.edu.my:8181/xmlui/handle/123456789/4200

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DC Field	Value	Language
dc.creator	Liu Yao Cho	-
dc.creator	Romero José Ricardo	-
dc.date	1998	-
dc.date.accessioned	2013-05-30T10:48:10Z	-
dc.date.available	2013-05-30T10:48:10Z	-
dc.date.issued	2013-05-30	-
dc.identifier	http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421998000200007	-
dc.identifier	http://www.doaj.org/doaj?func=openurl&genre=article&issn=01004042&date=1998&volume=21&issue=2&spage=144	-
dc.identifier.uri	http://koha.mediu.edu.my:8181/jspui/handle/123456789/4200	-
dc.description	beta-dicarbonyl compounds were oxidized electrocatalytically, with fragmentation and loss of "ch2", using ceric methanesulphonate as a mediator. 2,4-pentanedione yields acetic acid (90%), methyl acetoacetate yields acetic acid (84%) plus methanol and dimethyl malonate yields methanol (64%). For 1,3-diphenyl-1,3-propanedione and 1,3-cyclohexanedione, benzoic acid (61% yield) and glutaric acid (75% yield) were obtained, respectively. Methyl cyanoacetate and malononitrile were inert.	-
dc.publisher	Sociedade Brasileira de Química	-
dc.source	Química Nova	-
dc.subject	electrocatalysis	-
dc.subject	electrooxidation	-
dc.subject	ceric methanesulphonate	-
dc.title	Electrocatalytic oxidation of b-dicarbonyl compounds using ceric methanesulphonate as mediator	-
Appears in Collections:	Chemistry

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