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Title: Estudo cinético por TG e DSC da decomposição térmica de alguns adutos de haletos de cádmio
Keywords: thermal decomposition
kinetical parameters
cadmium adducts
Issue Date: 30-May-2013
Publisher: Sociedade Brasileira de Química
Description: By DSC data, the kinetical parameters Ea , n and A were calculated for the thermal decomposition of the adducts CdCl2.2dmf, CdCl2.dmf and CdBr2.dmf (dmf= dimethylformamide) by using Rogers and Smith method. The found values were : Ea = 85, 176 and 101 kJ mol-1 , n= 0.23, 0.25, and 0.17, A= 2.40x10(9), 1.89x10(19) and 1.07x10(9) respectively. By TGA data, the kinetical patameters for the thermal decomposition of the adduct CdCl2.1,5 dmeu (dmeu=dimethylethyleneurea) were calculated by using five different methods.
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Appears in Collections:Chemistry

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