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Frequency Dependence Modulus of Pd₄₀Ni₁₀Cu₃₀P₂₀ Amorphous Alloy around the Glass Transition by Dynamic Mechanical Analysis

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dc.creator Lee, M.L.
dc.creator Li, Yi
dc.creator Feng, Y.P.
dc.creator Carter, W. Craig
dc.date 2003-12-20T19:34:53Z
dc.date 2003-12-20T19:34:53Z
dc.date 2002-01
dc.date.accessioned 2013-10-09T02:33:21Z
dc.date.available 2013-10-09T02:33:21Z
dc.date.issued 2013-10-09
dc.identifier http://hdl.handle.net/1721.1/3973
dc.identifier.uri http://koha.mediu.edu.my:8181/xmlui/handle/1721
dc.description Dynamic Mechanical Analyzer (DMA) was used to study the frequency dependence of storage and loss modulus of amorphous Pd₄₀Ni₁₀Cu₃₀P₂₀ alloy over a broad frequency range around its glass transition temperature. The amorphous samples were subjected to two testing conditions: constant frequency with continuous heating and isothermal with frequency sweep. The storage modulus Eâ ² exhibited a sigmoidal change from about 90 GPa to a low value of about 0 GPa over the glass transition region. The loss modulus, Eâ ³, was characterized by an asymmetrical peak with a smaller slope at the low temperature side than at the high temperature side upon heating. These changes in moduli were associated with mechanical relaxation due to atomic motion. Similar results were also obtained under isothermal condition. The Kohrausch-Williams-Watts function was used to fit the data obtained under the isothermal condition. The peak frequencies obtained were then fitted to the VFT equation and the scaling law equation.
dc.description Singapore-MIT Alliance (SMA)
dc.format 1649377 bytes
dc.format application/pdf
dc.language en_US
dc.relation Advanced Materials for Micro- and Nano-Systems (AMMNS);
dc.subject Dynamic Mechanical Analyzer
dc.subject frequency dependence modulus
dc.subject amorphous Pd₄₀Ni₁₀Cu₃₀P₂₀ alloy
dc.subject Kohrausch-Williams-Watts function
dc.title Frequency Dependence Modulus of Pd₄₀Ni₁₀Cu₃₀P₂₀ Amorphous Alloy around the Glass Transition by Dynamic Mechanical Analysis
dc.type Article


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